A Novel Method for Generating Approximate Wavefunctions

نویسنده

  • B. Weiner
چکیده

Abstract Molecular Hamiltonians are constituted by momentum operators (e.g. kinetic energy and interaction with electro-magnetic radiation), local potential operators (e.g. electron-electron coulomb, electron-nucleus and electron-external field interactions) and spin operators. In general the effect of transformations that generate states from a reference state is to destroy this form. Here it is shown how one can generate all pure states by the action of a commutative semigroup of transformations that are diagonal in the space-spin coordinate representation that do not destroy this form and thus maintain the physical interpretability of effective Hamiltonians. Using such transformations we formulate an approximation theory that has physical interpretation at all orders.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Dirichlet series and approximate analytical solutions of MHD flow over a linearly stretching ‎sheet

The paper presents the semi-numerical solution for the magnetohydrodynamic (MHD) viscous flow due to a stretching sheet caused by boundary layer of an incompressible viscous flow. The governing partial differential equations of momentum equations are reduced into a nonlinear ordinary differential equation (NODE) by using a classical similarity transformation along with appropriate boundary cond...

متن کامل

A Novel Successive Approximation Method for Solving a Class of Optimal Control Problems

This paper presents a successive approximation method (SAM) for solving a large class of optimal control problems. The proposed analytical-approximate method, successively solves the Two-Point Boundary Value Problem (TPBVP), obtained from the Pontryagin's Maximum Principle (PMP). The convergence of this method is proved and a control design algorithm with low computational complexity is present...

متن کامل

Operation of Stand Alone PV Generating System for Supplying Unbalanced AC Loads

This paper describes a DC isolated network which is fed with Distributed Generation (DG) from photovoltaic (PV) renewable sources for supplying unbalanced AC loads. The battery energy storage bank has been connected to the DC network via DC/DC converter to control the voltage of the network and optimize the operation of the PV generation units. The PV arrays are connected to the DC network ...

متن کامل

FDiBC: A Novel Fraud Detection Method in Bank Club based on Sliding Time and Scores Window

One of the recent strategies for increasing the customer’s loyalty in banking industry is the use of customers’ club system. In this system, customers receive scores on the basis of financial and club activities they are performing, and due to the achieved points, they get credits from the bank. In addition, by the advent of new technologies, fraud is growing in banking domain as well. Therefor...

متن کامل

A Hybrid Neural Network Approach for Kinematic Modeling of a Novel 6-UPS Parallel Human-Like Mastication Robot

Introduction we aimed to introduce a 6-universal-prismatic-spherical (UPS) parallel mechanism for the human jaw motion and theoretically evaluate its kinematic problem. We proposed a strategy to provide a fast and accurate solution to the kinematic problem. The proposed strategy could accelerate the process of solution-finding for the direct kinematic problem by reducing the number of required ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2003